The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+Cl / CCl3O2 / Russell(1990)_296-460K_220-280nm

DATAFILE: CCl3O2_Russell(1990)_296-460K_220-280nm.txt
NAME: trichloromethylperoxy radical
FORMULA: CCl3O2
AUTHOR(YEAR): Russell(1990)
T: 296-460K
λ: 220-280nm
BIBLIOGRAPHY: J.J. Russell, J.A. Seetula, D. Gutman, F. Danis, F. Caralp, P.D. Lightfoot, R. Lesclaux, C.F. Melius, and S.M. Senkan, "Kinetics and thermochemistry of the equilibrium CCl3 + O2 ↔ CCl3O2", J. Phys. Chem. 94, 3277-3283 (1990); DOI: 10.1021/j100371a012
COMMENTS: Flash photolysis of molecular chlorine in the presence of chloroform and an excess of O2

Original results based on the calibration of the spectrum relative to that of CCl3 measured simultaneously

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